The two structures in plain terms
A PMP is a curated auction. The seller packages inventory, invites selected buyers, and sets a price floor. Delivery is not guaranteed — you win impressions when you clear the floor and your targeting allows it.
Programmatic guaranteed (PG) is a committed transaction. The seller guarantees a defined volume of impressions at a fixed CPM for a defined flight, and you commit to buying it. It behaves like a direct buy, but it is transacted and trafficked programmatically through a deal ID.